Extraction-Spectrophotometric Determination of Cadmium with N-Hydroxy-N,N'-diphenylbenzamidine and 4-(2-Pyridylazo)resorcinol.
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Spectrophotometric Determination of 4-Hydroxy-2-mercapto-6-methylpyrimidine Based on Aggregation of Colloidal Gold Nanoparticles
We report herein the development of a highly sensitive colorimetric method for the detection of 4-hydroxy-2-mercapto-6-methylpyrimidine (MTU) which acts as an anti-thyroid drug utilizing citrate capped gold nanoparticles (Au-NPs). This thiol-containing molecule exhibits intriguing affinity with Au-NPs. The reactivity involves the displacement of the citrate shell by the thiolate shell followed ...
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A new chromogenic reagent, 5-(2-hydroxy-5-nitrophenylazo)thiorhodanine (HNATR) was synthesized. A highly sensitive, selective and rapid method for the determination microg l(-1) level of Au(III) based on the rapid reaction of Au(III) with HNATR and the solid phase extraction of the colored complex with a reversed phase polymer-based C(18) cartridge have been developed. The HNATR reacted with Au...
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we report herein the development of a highly sensitive colorimetric method for the detection of 4-hydroxy-2-mercapto-6-methylpyrimidine (mtu) which acts as an anti-thyroid drug utilizing citrate capped gold nanoparticles (au-nps). this thiol-containing molecule exhibits intriguing affinity with au-nps. the reactivity involves the displacement of the citrate shell by the thiolate shell followed ...
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A solvent-extraction spectrophotometric technique is proposed as a new method for determination of trace quantities of vanadium. Sodium salt of 2-mercapto-pyridine-N-oxide (thione) forms a complex with vanadium instantaneously. The purple 1:2 complex is formed of pH 2.3, easily extracted in chloroform and shows strong absorbance at 500 nm. The extracted complex is found to obey Beer's law i...
متن کاملExtraction - Spectrophotometric Determination of Palladium with Tetrabutyl Ammonium Iodide
A sensitive and selective extraction - spectrophotometric method for the determination of trace amounts of palladium is reported. The method is based on quantitative extraction of brownish tetrabutylammoium tetraiodopalladium (II) ion pair into a small valume of chloroform at pH 1.3-12.0, followed by spectrophotometric measurements. The Beer's law is obeyed over the range 0.02-1.09 <em...
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ژورنال
عنوان ژورنال: Analytical Sciences
سال: 1992
ISSN: 0910-6340,1348-2246
DOI: 10.2116/analsci.8.609